Please note that this is my very first tutorial I've done.
So I am sorry if some things are a bit confusing...
If you have any questions, just ask in a comment.
The letter in () are the shortcut to the tool needed.
I'm using Adobe Photoshop Elements 2.0.
But it should be pretty much the same in every Photoshop, even CS.
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Choose the picture you want.
Now zoom in on the eyes, either using the zoom tool (z) or hit ctrl+.
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Choose the Lasso Tool, make sure it's set on Magnetic Lasso Tool.
You just right click on the Lasso Tool and choose Magnetic.
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Once you have the Magnetic Lasso Tool chosen make sure it's
set on Add To Selection and that Feather is on 5px.
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Now it's time to select those eyes in order to make them "pop" later !!
By choosing the setting Add to selection you can mark the other eye
without un-marking the first one you marked.
Just make a start point at the outline of the iris and then you follow it.
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Don't worry if it doesn't become perfect with the selection,
we're going to take care of that in step four.
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Hm, that doesn't look good, now does it ? Not to worry !!
Choose the Selection Brush Tool (A) and just fix it.
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Now when you have the eyes selected you're going to copy them
and make a new layer with that copy.
Just hit ctrl+c and then ctrl+v.
Tips; Have the Move Tool (V) selected when doing this.
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You should now have a new layer, being the eyes alone.
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Go to Filter Meny -> Other -> Highpass
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I personally prefer to have it set on 20 pixels.
But you can of course try your way forward to see what you want.
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Looks a bit... bad right now.
This is where you make the Eyes layer set on Soft Light.
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And you're done !!
If you are thinking "Hm, it doesn't look any diffirent..."
Just hide the eye layer and have a look. You can do this
by clicking on the "eye" to the left of the layer.
Hope it helped and have fun making those eye "pop" !! ^^